PDF (1319K)
摘要
介绍了纳米级ZSM-5分子筛的制备方法，分析了纳米尺度ZSM-5分子筛的优缺点。指出开发优异的甲醇制丙烯ZSM-5分子筛的关键在于控制一个维度上达到纳米尺度、减少缺陷位、控制Al分布以减少外表面酸性位，并要兼顾多方面因素来调节ZSM-5分子筛，才能有望得到MTP反应催化性能优异的ZSM-5分子筛。
Abstract
The preparation methods for nano-scale ZSM-5 molecular sieve are introduced and the advantages and disadvantages of nano-scale ZSM-5 molecular sieve are analyzed.It is pointed out that the keys to develop excellent ZSM-5 molecular sieve for methanol to propylene (MTP) include controlling nano-scale of the molecular sieve on one dimension,reducing defect sites,controlling Al distribution in order to reduce the external surface acidic sites and adjusting ZSM-5 molecular sieve by considering various factors,and then the ZSM-5 molecular sieve with excellent catalytic performance in MTP reaction can be obtained.
关键词
纳米尺度
/
甲醇制烯烃
/
缺陷位
/
酸分布
/
扩散
/
ZSM-5分子筛
Key words
nano-scale
/
methanol to olefins
/
defect site
/
acid site distribution
/
diffusion
/
ZSM-5 molecular sieve
Author summay
缪平(1963-),男,博士,主任工程师,主要从事导电高分子材料、电子封装、制药工艺、精细化学工艺、催化剂等领域的研究和管理工作,miaoping@nicenergy.com
纳米级ZSM-5分子筛的制备及其在甲醇制丙烯反应中的优势与劣势[J].
, 2018, 38(5): 48-52 DOI:10.16606/j.cnki.issn0253-4320.2018.05.011
