在切割温度90℃下对FCC汽油进行馏分切割。采用氧化-吸附工艺脱除FCC汽油重馏分中的硫化物。以H₂O₂为氧化剂，HCOOH-H₂SO₄杂多酸为催化剂，抚顺二厂混合平衡催化剂为吸附剂，考察工艺条件对脱硫效果的影响，并对脱硫前后油品的硫类型分布进行检测分析。结果表明，在V（H₂O₂）：V（H₂SO₄）：V（HCOOH）=23：1.5：3、氧化温度为60℃、m（吸附剂）：m（油）=0.5、吸附温度为70℃、吸附时间为60 min的条件下，体系脱硫率为72.4%。

Fractions of FCC gasoline are cut at 90℃.Sulfides are removed from heavy fractions of FCC gasoline by oxidation-adsorption process.The influence of technological conditions on the desulfurization efficiency is investigated by using H₂O₂ as oxidant,HCOOH-H₂SO₄ heteropoly acid as catalyst and the self-made hybrid equilibrium catalyst as adsorbent.The sulfur type distribution in the oil products before and after desulfurization is detected and analyzed.The results show that the desulfurization rate can reach 72.4% under the conditions of v(H₂O₂):V(H₂SO₄):v(HCOOH)=23:1.5:3,oxidation temperature 60℃,m(adsorbent):m(oil)=0.5,adsorption temperature 70℃ and adsorption time 60 min.

刘思彤(1993-),女,硕士研究生,研究方向为清洁燃料生产,349435294@qq.com