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摘要
以CO2与环氧化物合成环状碳酸酯为研究对象,综述了有机碱催化剂、碱金属卤化物催化剂、酸碱性催化剂、金属配合物催化剂、杂多酸盐催化剂、离子液体催化剂6类均相催化剂的研究进展,并就其催化活性进行了比较,探讨了未来均相催化剂的发展前景。
Abstract
Taking the synthesis of cyclic carbonates from carbon dioxide and epoxides as study object,this paper reviews the research progress on six kinds of homogeneous catalysts including organic base catalysts,alkali metal halides catalysts,acid and base catalysts,metal complex catalysts,polyoxometalates catalysts and ionic liquid catalysts.The comparison between them has been carried out.In addition,the prospect for homogeneous catalysts in the future is discussed.
关键词
环状碳酸酯
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环氧化物
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CO2
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均相催化剂
Key words
cyclic carbonates
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epoxide
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carbon dioxide
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homogeneous catalysts
Author summay
均相催化剂催化CO2与环氧化物合成环状碳酸酯的研究进展[J].
, 2017, 37(10): 60-64 DOI:10.16606/j.cnki.issn0253-4320.2017.10.014