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现代化工  2022, Vol. 42 Issue (7): 130-134,140    DOI: 10.16606/j.cnki.issn0253-4320.2022.07.026
  科研与开发 本期目录 | 过刊浏览 | 高级检索 |
Co/Si/Mo/Ni/Al2O3催化剂对汽油加氢脱硫性能的影响
田鑫, 李欣, 王薇, 吕鹏, 马保军
宁夏大学省部共建煤炭高效利用与绿色化工国家重点实验室, 宁夏 银川 750021
Effect of Co/Si/Mo/Ni/Al2O3 catalyst on performance of gasoline hydrodesulfurization
TIAN Xin, LI Xin, WANG Wei, LV Peng, MA Bao-jun
State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, Ningxia University, Yinchuan 750021, China
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摘要 为了研究活性组分的负载对催化剂加氢脱硫性能的影响,设计并制备了Co/Si/Mo/Ni/Al2O3多元复合催化剂。通过固定床催化剂评价装置对其进行二苯并噻吩加氢脱硫反应活性评价,并利用X射线衍射仪(XRD)、N2吸附测试仪、X射线光电子能谱仪(XPS)、扫描电子显微镜(SEM)和Mapping等分析测试手段对催化剂进行表征。结果表明,复合催化剂具有优良的加氢脱硫性能,当活性组分负载量为(0.5% Co)/(1.5% Si)/(3.0% Mo)/(10.0% Ni)/Al2O3时,其加氢脱硫性能最高可达到96.1%。
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田鑫
李欣
王薇
吕鹏
马保军
关键词:  多元复合催化剂  加氢脱硫  固定床  二苯并噻吩  活性组分    
Abstract: In order to study the effect of active component loading on the hydrodesulfurization performance of the catalyst,Co/Si/Mo/Ni/Al2O3 composite catalyst is designed and prepared.The activity of the catalyst in hydrodesulfurization of dibenzothiophene is evaluated through a fixed bed catalyst evaluation device,and the catalyst is characterized by X-ray diffraction (XRD),N2 adsorption,X-ray photoelectron spectroscopy (XPS),scanning electron microscopy (SEM) and Mapping.The results show that the composite catalyst has excellent hydrodesulfurization performance.The highest hydrodesulfurization performance can reach 96.1% when the loading amount of active component is (0.5% Co)/(1.5% Si)/(3.0% Mo)/(10.0% N)/Al2O3.
Key words:  multicomponent composite catalyst    hydrodesulfurization    fixed bed    dibenzothiophene    active component
收稿日期:  2021-07-14      修回日期:  2022-05-02           出版日期:  2022-07-20
ZTFLH:  O643.36  
基金资助: 国家自然科学基金(21862014);宁夏重点研发计划项目(2019BDE03003);宁夏科技创新团队项目(2020CXTDLX08)
通讯作者:  马保军(1973-),男,博士后,研究员,研究方向为氢能清洁生产与高附加值转化,bjma@nxu.edu.cn。    E-mail:  bjma@nxu.edu.cn。
作者简介:  田鑫(1998-),女,硕士研究生,研究方向为二氧化碳高附加值转化,Txin19980130@163.com
引用本文:    
田鑫, 李欣, 王薇, 吕鹏, 马保军. Co/Si/Mo/Ni/Al2O3催化剂对汽油加氢脱硫性能的影响[J]. 现代化工, 2022, 42(7): 130-134,140.
TIAN Xin, LI Xin, WANG Wei, LV Peng, MA Bao-jun. Effect of Co/Si/Mo/Ni/Al2O3 catalyst on performance of gasoline hydrodesulfurization. Modern Chemical Industry, 2022, 42(7): 130-134,140.
链接本文:  
https://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2022.07.026  或          https://www.xdhg.com.cn/CN/Y2022/V42/I7/130
[1] 杨轶博,张思懿,王轲,等.包覆型Hβ和MCM-41复合分子筛作载体制备Pt加氢脱硫催化剂的研究[J].现代化工,2021,41(6):101-105.
[2] Laurenti D,Phung-Ngoc B,Rooukoss C,et al.Intrinsic potential of alumina-supported CoMo catalysts in HDS:Comparison between γc,γT,and δ-alumina[J].Journal of Catalysis,2013,297:165-175.
[3] Song H,Wang J,Wang Z,et al.Effect of titanium content on dibenzothiophene HDS performance over Ni2P/Ti-MCM-41 catalyst[J].Journal of Catalysis,2014,311:257-265.
[4] Gao Q,Ofosu T N,Ma S G,et al.Catalyst development for ultra-deep hydrodesulfurization (HDS) of dibenzothiophenes.Ⅰ:Effects of Ni promotion in molybdenum-based catalysts[J].Catalysis Communications,2011,164:538-543.
[5] Wang Y,Lancelot C,Lamonier C,et al.Hierarchization of mordenite as NiW sulfide catalysts support:Towards efficient hydrodesulfurization[J].ChemCatChem,2015,7:3936-3944.
[6] Calderon-Magdaleon M A,Mendoza-Nieto J A,Klimova T E.Effect of the amount of citric acid used in the preparation of NiMo/SBA-15 catalysts on their performance in HDS of dibenzothiophene-type compounds[J].Catalysis Communications,2014,220:78-88.
[7] Fan J,Duan A,Xu C,et al.Hydrodesulfurization properties of dibenzothiophene over NiMo catalysts supported on cubic Fm3m mesoporous structure and high-framework aluminum-modified AlKIT-5[J].Energy&Fuels,2018,32:9793-9803.
[8] Xie K,Fang Y,Liu B,et al.Enhanced catalytic activity of monodispersed porous Al2O3 colloidal spheres with NiMo for simultaneous hydrodesulfurization and hydrogenation[J].Royal Society of Chemistry Advances,2018,8:18059-18066.
[9] 杨靖,陈杰,刘春晓.二氧化硅溶胶的制备及性能影响研究[J].辽宁化工,2007,4(36):217-220.
[10] Yang K,Chen X,Qi J,et al.A highly efficient and sulfur-tolerant Pd2Si/CNTs catalyst for hydrodesulfurization of dibenzothiophenes[J].Journal of Catalysis,2019,369:363-371.
[11] Mo S,Zhang Q,Ren Q.Leaf-like Co-ZIF-L derivatives embedded on Co2AlO4/Ni foam from hydrotalcites as monolithic catalysts for toluene abatement[J].Journal of Hazardous Materials,2019,364:571-580.
[12] Siahvashi,Arman,Chesterfield,et al.Propane CO2(dry) reforming over bimetallic Mo-Ni/Al2O3 catalyst[J].Chemical Engineering Science,2013,93:313-325.
[13] Gonzalezcortes S,Xiao T C,Rodulfobaechler S.Impact of the urea-matrix combustion method on the HDS performance of Ni-MoS/γ-AlO catalysts[J].Journal of Molecular Catalysis A Chemical,2005,240(1):214-225.
[14] Liu L,Liu B,Chai Y.Synergetic effect between sulfurized Mo/γ-AlO and Ni/γ-AlO catalysts in hydrodenitrogenation of quinolone[J].Journal of Energy Chemistry,2011,20(2):214-217.
[15] Li J,Gao L,Zheng S.SEM,XPS,and FT-IR studies of MoO3 dispersion on mesoporous silicate MCM-41 by calcination[J].Materials Letters,2003,57:4605-4610.
[16] Senthilkumar B,Meyrick D,Lee Y S,et al.Synthesis and improved electrochemical performances of nano β-NiMoO4-CoMoO4·xH2O composites for asymmetric supercapacitors[J].Royal Society of Chemistry Advances,2013,3(37):16542-16548.
[17] 华益苗,袁骏,岳林海,等.SiO2包覆超细CaCO3的微晶分析和XPS研究[J].无机化学学报,2001,01:134-138.
[18] Frederick N,Daniel A A,Jeong I H.Facilely synthesized NiMoO4/CoMoO4 nanorods as electrode material for high performance supercapacitor[J].Journal of Alloys and Compounds,2018,742:342-350.
[19] Mo S,Zhang Q,Ren O.Leaf-like Co-ZIF-L derivatives embedded on Co2AlO4/Ni foam from hydrotalcites as monolithic catalysts for toluene abatement[J].Journal of Hazardous Materials,2019,364:571-580.
[20] Volochaev M N,Komogortsev S V,Myagkov V G.Structural and magnetic characteristics of nanogranular Co-Al2O3 single-and multilayer films formed by the solid-state synthesis[J].Physics of the Solid State,2018,60(7):1425-1431.
[21] Wu F,Tian W,Cao F.Loading amorphous NiMoO4-xS<i>x nanosheet cocatalyst to improve performance of p-silicon wafer photocathode[J].Journal of the American Chemical Society Applied Energy Materials,2018,1(3):1286-1293.
[22] Ray S K,Dhakal D,Regmi C.Inactivation of staphylococcus aureus in visible light by morphology tuned α-NiMoO4[J].Journal of Photochemistry&Photobiology A Chemistry,2018,350:59-68.
[23] Li P,Ruan C,Xu J.Enhanced capacitive performance of CoO-modified NiMoO4 nanohybrid as advanced electrodes for asymmetric supercapacitor[J].Journal of Alloys and Compounds,2019,791:152-165.
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