Conversion of fructose into 5-hydroxymethylfurfural over carbon-silicon supported niobium oxide
YANG Feng-li1, ZHAO Zhi-yan1, TONG Xue2
1. School of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou 213000, China; 2. School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China
Abstract: Nb2O5/C-Si is prepared and its catalytic properties in conversion of biomass sugar to 5-hydroxymethylfurfural (HMF) are studied.The factors such as niobium oxide loading amount,reaction time,temperature and catalyst dosage are investigated.It is found the niobium oxide loading amount has important impact on the acidity amount and catalytic properties of the catalyst,and the selectivity of HMF.With the increase of niobium oxide loading amount,both the acidity amount of catalyst and the conversion rate of fructose increase while the selectivity of HMF increases firstly and decreases then.The highest yield of HMF can reach 82.8% over 5% Nb2O5/P-C-Si catalyst.
杨凤丽, 赵芷言, 仝雪. 碳硅负载氧化铌催化果糖制备5-羟甲基糠醛的研究[J]. 现代化工, 2019, 39(10): 70-75.
YANG Feng-li, ZHAO Zhi-yan, TONG Xue. Conversion of fructose into 5-hydroxymethylfurfural over carbon-silicon supported niobium oxide. Modern Chemical Industry, 2019, 39(10): 70-75.
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