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现代化工  2019, Vol. 39 Issue (6): 144-148    DOI: 10.16606/j.cnki.issn0253-4320.2019.06.030
  科研与开发 本期目录 | 过刊浏览 | 高级检索 |
微波辅助餐厨垃圾制备生物柴油
钟昌东, 梁客, 李爱蓉
西南石油大学化学化工学院, 四川 成都 610500
Preparation of biodiesel from kitchen waste assisted by microwave
ZHONG Chang-dong, LIANG Ke, LI Ai-rong
College of Chemistry & Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China
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摘要 以餐厨垃圾为原料,在微波辅助下直接制备生物柴油,通过单因素实验优化生物柴油的制备条件,同时利用气相色谱-质谱联用分析产物的组成及含量。实验结果表明,在餐厨垃圾样品质量为5 g、反应时间为20 min、反应温度为55℃、浓硫酸质量为2.0 g、甲醇用量为55 mL、微波功率为700 W时,酯化反应的最高转化率为65.11%,且产物中脂肪酸甲酯质量分数达到97.03%。
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钟昌东
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李爱蓉
关键词:  餐厨垃圾  微波  生物柴油  转化率  酸值    
Abstract: Biodiesel is directly produced from kitchen wastes with assistance of microwave.Production parameters are optimized via single factor experiment analysis,and the composition and content of biodiesel are analyzed by gas chromatography-mass spectrometry.Experimental results show that the maximum conversion rate can reach 65.11% and the content of fatty acid methyl ester in biodiesel can reach 97.03% when the amount of kitchen wastes is 5 g,the reaction lasts for 20 min,the temperature is set at 55℃,the amount of sulfuric acid is 2.0 g,the dosage of methanol is 55 mL and microwave power is 700 W.
Key words:  kitchen wastes    microwave    biodiesel    conversion rate    acid number
收稿日期:  2018-10-09      修回日期:  2019-04-03          
ZTFLH:  TQ645.6  
基金资助: 四川省科技厅应用基础研究资助项目(2016JY0176)
通讯作者:  李爱蓉(1980-),女,博士研究生,副教授,研究方向为天然气水合物开采及绿色化工清洁生产过程,通讯联系人,liairong@swpu.edu.cn。    E-mail:  liairong@swpu.edu.cn
作者简介:  钟昌东(1994-),男,硕士研究生,研究方向为废油脂的提取及生物柴油的制备,1532616143@qq.com
引用本文:    
钟昌东, 梁客, 李爱蓉. 微波辅助餐厨垃圾制备生物柴油[J]. 现代化工, 2019, 39(6): 144-148.
ZHONG Chang-dong, LIANG Ke, LI Ai-rong. Preparation of biodiesel from kitchen waste assisted by microwave. Modern Chemical Industry, 2019, 39(6): 144-148.
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http://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2019.06.030  或          http://www.xdhg.com.cn/CN/Y2019/V39/I6/144
[1] Baesso R M,Oliveira P A,Morais G C,et al.Using ultrasonic velocity for monitoring and analysing biodiesel production[J].Fuel,2018,226:389-399.
[2] Sivaramakrishnan R,Incharoensakdi A.Microalgae as feedstock for biodiesel production under ultrasound treatment-A review[J].Bioresource Technology,2018,250:877-887.
[3] 方正,吕德义.微藻制备生物柴油的研究进展[J].现代化工,2017,37(9):57-61.
[4] Soto F,Alves M,Valdés J C,et al.The determination of the activation energy of diesel and biodiesel fuels and the analysis of engine performance and soot emissions[J].Fuel Processing Technology,2018,174:69-77.
[5] Hanif M A,Nisar S,Akhtar M N,et al.Optimized production and advanced assessment of biodiesel:A review[J].International Journal of Energy Research,2018,(4):2070-2083.
[6] Zhao Z,Xue Y,Xu G,et al.Reaction conditions of ultrasound-assisted production of biodiesel:A review[J].International Journal of Energy Research,2016,41(8):1081-1095.
[7] 郑万刚,汪树军,刘红研,等.生物柴油低温流动改进剂的制备及其降滤效果评价[J].化工学报,2014,65(4):1481-1487.
[8] Jiaqiang E,Pham M,Zhao D,et al.Effect of different technologies on combustion and emissions of the diesel engine fueled with biodiesel:A review[J].Renewable & Sustainable Energy Reviews,2017,80:620-647.
[9] Varun,Singh P,Tiwari S K,et al.Modification in combustion chamber geometry of CI engines for suitability of biodiesel:A review[J].Renewable & Sustainable Energy Reviews,2017,79:1016-1033.
[10] Carareto N D D,Kimura C Y C S,Oliveira E C,et al.Flash points of mixtures containing ethyl esters or ethylic biodiesel and ethanol[J].Fuel,2011,90(7):319-326.
[11] Sharma Y C,Singh B,Upadhyay S N.Advancements in development and characterization of biodiesel:A review[J].Fuel,2008,87(12):2355-2373.
[12] Jakeria M R,Fazal M A,Haseeb A S M A.Influence of different factors on the stability of biodiesel:A review[J].Renewable & Sustainable Energy Reviews,2014,30(2):154-163.
[13] Aransiola E F,Ojumu T V,Oyekola O O,et al.A review of current technology for biodiesel production:State of the art[J].Biomass & Bioenergy,2014,61(1):276-297.
[14] Kiss A A,Bildea C S.A review of biodiesel production by integrated reactive separation technologies[J].Journal of Chemical Technology & Biotechnology,2012,87(7):861-879.
[15] 吴慧娟,许世海,张文田.生物柴油研究与应用现状[J].现代化工,2007,27(s1):20-23.
[16] Asadi M,Lupton D W,Hooper J F.Biodiesel synthesis using integrated acid and base catalysis in continuous flow[J].Tetrahedron,2016,72(26):3729-3733.
[17] Suh W I,Mishra S K,Kim T H,et al.Direct transesterification of wet microalgal biomass for preparation of biodiesel[J].Algal Research,2015,12(C):405-411.
[18] 侯佳玲,惠岚峰,刘鹏涛.磺化活性炭球在废油脂制生物柴油中催化性能的研究[J].现代化工,2017,(1):118-122.
[19] Nasreen S,Liu H,Skala D,et al.Preparation of biodiesel from soybean oil using La/Mn oxide catalyst[J].Fuel Processing Technology,2015,131:290-296.
[20] 黄振旭,裴先茹,孙海杰,等.大豆油制备生物柴油KF/ZrO2固体碱催化剂性能研究[J].现代化工,2018,(2):95-97.
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