Research progress of non-noble metal catalysts for catalytic combustion of BTX
YE Jun-hui1, ZHANG Xiao-lan1, YUAN Jing2, CAI Ting1,2, HE Dan-nong1,2
1. School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China; 2. National Engineering Research Center for Nanotechnology, Shanghai 200241, China
Abstract: Non-noble metal catalysts for catalytic combustion of benzene,toluene and xylene (BTX) in recent years are comprehensively summarized,including transition metal oxide catalysts,perovskite-type catalysts and spinel-type catalysts.The typical mechanisms of non-noble metal catalysts for catalytic combustion of BTX are discussed.Finally,based on the reaction mechanism of catalytic combustion combining with practical examples,the further research focus and directions of non-noble metal catalysts for catalytic combustion of BTX are proposed.
叶俊辉, 张晓岚, 袁静, 蔡婷, 何丹农. 非贵金属催化剂用于BTX催化燃烧的研究进展[J]. 现代化工, 2018, 38(3): 18-22.
YE Jun-hui, ZHANG Xiao-lan, YUAN Jing, CAI Ting, HE Dan-nong. Research progress of non-noble metal catalysts for catalytic combustion of BTX. Modern Chemical Industry, 2018, 38(3): 18-22.
[1] 朱世勇.环境与工业气体净化[M].北京:化学工业出版社,2011:502. [2] 牛茜,李兵,徐校良,等.催化燃烧处理挥发性有机化合物研究进展[J].现代化工,2013,33(11):19-23. [3] Tang W X,Deng Y Z,Li W H,et al.Restrictive nanoreactor for growth of transition metal oxides (MnO2,Co3O4,NiO) nanocrystal with enhanced catalytic oxidation activity[J].Catalysis Communications,2015,72:165-169. [4] Fei Z Y,Lu P,Feng X Z,et al.Geometrical effect of CuO nanostructures on catalytic benzene combustion[J].Catalysis Science & Technology,2012,2:1705-1710. [5] Lin T,Yu L,Sun M,et al.Mesoporous α-MnO2 microspheres with high specific surface area:Controlled synthesis and catalytic activities[J].Chemical Engineering Journal,2016,286:114-121. [6] Jiang S J,Liu F,Liao Y T,et al.Effect of doping the nitrogen into carbon nanotubes on the activity of NiO catalysts for the oxidation removal of toluene[J].Applied Catalysis B:Environmental,2014,160/161:716-721. [7] Zhou G L,Lan H,Wang H,et al.Catalytic combustion of PVOCs on MnOx catalysts[J].Journal of Molecular Catalysis A:Chemical,2014,393:279-288. [8] Wang H,Liu M,Guo S H,et al.Efficient oxidation of o-xylene over CeO2 catalyst prepared from a Ce-MOF template:The promotion of K+ embedding substitution[J].Molecular Catalysis,2017,436:120-127. [9] Yang P,Li J R,Zuo S F.Promoting oxidative activity and stability of CeO2 addition on the MnOx modified kaolin-based catalysts for catalytic combustion of benzene[J].Chemical Engineering Science,2017,162:218-226. [10] Zuo S F,Liu F J,Tong J,et al.Complete oxidation of benzene with cobalt oxide and ceria using the mesoporous support SBA-16[J].Applied Catalysis A:General,2013,467:1-6. [11] Li W B,Liu Z X,Liu R F,et al.Rod-like CuMnOx transformed from mixed oxide particles by alkaline hydrothermal treatment as a novel catalyst for catalytic combustion of toluene[J].Physical Chemistry Chemical Physics,2016,18(33):22794-22798. [12] 杜琴香,周桂林,杨瑶.焙烧温度对CeCu氧化物催化剂上苯基挥发性有机物催化燃烧的影响[J].石油化工,2015,44(8):1002-1008. [13] 魏倩.铜、银掺杂OMS-2催化剂的制备及对邻二甲苯深度催化氧化的研究[D].石家庄:河北师范大学,2014. [14] Yang J S,Jung W Y,Lee G D,et al.Catalytic combustion of benzene over metal oxide supported on SBA-15[J].Journal of Industrial and Engineering Chemistry,2008,14(6):779-784. [15] Kim S C,Shim W G.Catalytic combustion of VOCs over a series of manganese oxide catalysts[J].Applied Catalysis B:Environmental,2010,98(3/4):180-185. [16] Tang W X,Wu X F,Liu G,et al.Preparation of hierarchical layer-stacking Mn-Ce composite oxide for catalytic total oxidation of VOCs[J].Journal of rare earths,2015,33(1):62-69. [17] 俞丹青.钛基催化剂催化氧化苯系物有机废气的研究[D].杭州:浙江大学,2010. [18] Ma C Y,Mu Z,He C,et al.Catalytic oxidation of benzene over nanostructured porous Co3O4-CeO2 composite catalysts[J].Journal of Environmental Sciences,2011,23(12):2078-2086. [19] Wang Z,Shen G L,Li J Q,et al.Catalytic removal of benzene over CeO2-MnOx composite oxides prepared by hydrothermal method[J].Applied Catalysis B:Environmental,2013,(138):253-259. [20] Wang X Y,Zuo J C,Luo Y J,et al.New route to CeO2/LaCoO3 with high oxygen mobility for total benzene oxidation[J].Applied Surface Science,2017,396:95-101. [21] Tarjomannejad A,Farzi A,Niaei A,et al.An experimental and kinetic study of toluene oxidation over LaMn1-xBxO3 and La0.8A0.2Mn0.3B0.7O3 (A=Sr,Ce and B=Cu,Fe) nano-perovskite catalysts[J].Korean Journal of Chemical Engineering,2016,33(9):2628-2637. [22] Alifnam M,Florea M,Rvulescu P V I.Ceria-based oxides as supports for LaCoO3 perovskite;catalysts for total oxidation of VOC[J].Applied Catalysis B:Environmental,2007,70(1/2/3/4):400-405. [23] Wang X Y,Liu Y,Zhang T H,et al.Geometrical-site-dependent catalytic activity of ordered mesoporous Co-based spinel for benzene oxidation:In situ drifts study coupled with raman and XAFS spectroscopy[J].ACS Catalysis,2017,(7):1626-1636. [24] Siham B,Philippe G,Pierre A,et al.New synthesis of nanosized Cu-Mn spinels as efficient oxidation catalysts[J].Catalysis Today,2012,189:35-41. [25] Tang W X,Deng Y Z,Li W H,et al.Importance of porous structure and synergetic effect on the catalytic oxidation activities over hierarchical Mn-Ni composite oxides[J].Catalysis Science & Technology,2015,6(6):1710-1718. [26] Li N,Bor Ave A,Deloume J P,et al.Catalytic combustion of toluene over a Sr and Fe substituted LaCoO3 perovskite[J].Solid State Ionics,2008,179(27/28/29/20/31/32):1396-1400. [27] Zhang C H,Guo Y L,Guo Y,et al.LaMnO3 perovskite oxides prepared by different methods for catalytic oxidation of toluene[J].Applied Catalysis B:Environmental,2014,148:490-498. [28] Anne G F,Maira A F,Melissandre R,et al.Synthesis of oxide supported LaMnO3 perovskites to enhance yields in toluene combustion[J].Applied Catalysis B:Environmental,2016,(180):29-37. [29] Li T Y,Chiang S J,Liaw B J,et al.Catalytic oxidation of benzene over CuO/Ce1-xMnxO2 catalysts[J].Applied Catalysis B:Environmental,2011,103(1/2):143-148. [30] 孔娴鹇.Cu-Mn-Ce催化剂的制备及其催化燃烧VOCs的性能研究[D].杭州:浙江工业大学,2014. [31] Wu H J,Wang L D,Zhang J Q,et al.Catalytic oxidation of benzene,toluene and p-xylene over colloidal gold supported on zinc oxide catalyst[J].Catalysis Communications,2011,(12):859-865.