Research progress of catalyst for propane dehydrogenation to make propylene
LI Si-xuan1,2, ZHANG Hui-min3, XIA Lei2, WEI Bo1,2, YANG Ya-xin1,2, WANG Hong2, LI Cui-qing2, SONG Yong-ji2
1. College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China; 2. School of Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China; 3. Department of CTL and Coal to Chemicals, Shenhua Group Corporation Limited, Beijing 100011, China
Abstract: The patented technologies,thermodynamic characteristics and reaction mechanisms of the industrial propane dehydrogenation (PDH) process are outlined in this paper.The Pt-series or Cr-series catalysts are used for PDH process.The advances of catalysts are reviewed from the type of carriers and the selection of auxiliaries respectively according to the advantages and shortages of these two series catalysts,and the coking problem of catalysts is analyzed.
李思漩, 张惠民, 夏蕾, 魏波, 杨亚馨, 王虹, 李翠清, 宋永吉. 丙烷脱氢制丙烯催化剂研究进展[J]. 现代化工, 2018, 38(2): 14-19,21.
LI Si-xuan, ZHANG Hui-min, XIA Lei, WEI Bo, YANG Ya-xin, WANG Hong, LI Cui-qing, SONG Yong-ji. Research progress of catalyst for propane dehydrogenation to make propylene. Modern Chemical Industry, 2018, 38(2): 14-19,21.
[1] 刘昌呈,王春明,马爱增.工艺条件对Pt-Sn-K/Al2O3催化剂丙烷脱氢性能的影响[J].石油炼制与化工,2013,44(4):34-38. [2] 张海娟,王振宇,李江红,等.反应条件对丙烷脱氢催化剂积炭行为的影响[J].天然气化工:C1化学与化工,2014,39(2):38-42. [3] Sattler J J H B,Ruiz-Martinez J,Santillan-Jimenez E,et al.Catalytic dehydrogenation of light alkanes on metals and metal oxides[J].Chemical Reviews,2014,114(20):10613-10653. [4] Zhang Y W,Zhou Y M,Wan L H,et al.Effect of magnesium addition on catalyticperformance of PtSnK/γ-Al2O3,catalyst for isobutene dehydrogenation[J].Fuel Processing Technology,2011,92(8):1632-1638. [5] Feng J,Zhang M S,Yang Y Y.Dehydrogenation of propane on Pt or PtSn catalysts with Al2O3 or SBA-15 support[J].Chinese Journal of Chemical Engineering,2014,22:1232-1236. [6] Xia K,Lang W Z,Li P P,et al.The influences of Mg/Al molar ratio on the properties of PtIn/Mg(Al)Ox,catalysts for propane dehydrogenation reaction[J].Chemical Engineering Journal,2016,284:1068-1079. [7] Wang Y J,Wang Y M,Wang S R,et al.Propane dehydrogenation over PtSn catalysts supported on ZnO-Modified MgAl2O4[J].Catalysis Letters,2009,132(3/4):472-479. [8] Nawaz Z S,Tang X P,Zhang Q,et al.SAPO-34 supported Pt-Sn-based novel catalyst for propane dehydrogenation to propylene[J].Catalysis Communications,2009,10(14):1925-1930. [9] Zhou H L,Gong J J,Xu B L,et al.PtSnNa/SUZ-4:An efficient catalyst for propane dehydrogenation[J].Chinese Journal of Catalysis,2017,38(3):529-536. [10] Li B,Xu Z X,Chu W,et al.Ordered mesoporous Sn-BA-15 as support for Pt catalyst with enhanced performance in propane dehydrogenation[J].Chinese Journal of Catalysis,2017,38:726-735. [11] 余长林,葛庆杰,徐恒泳,等.助剂对Pt/γ-Al2O3催化剂丙烷脱氢性能的影响[J].石油化工,2006,35(3):217-220. [12] Lee M H,Nagaraja B M,Natarajan P,et al.Effect of potassium addition on bimetallic PtSn/θ-Al2O3 catalyst for dehydrogenation of propane to propylene[J].Research on Chemical Intermediates,2016,42(1):123-140. [13] 冯静,张明森,杨元一.助剂对PtSn/SBA-15催化剂丙烷脱氢性能的影响[J].石油化工,2014,43(12):1370-1374. [14] Liu J,Liu C C,Ma A Z,et al.Effects of Al2O3 phase and Cl component on dehydrogenation of propane[J].Applied Surface Science,2016,368:233-240. [15] 柏凌,陈功东,刘程,等.丙烷直接脱氢制丙烯的催化剂研究进展[J].现代化工,2015,35(8):23-27. [16] 谭晓林,马波,张喜文,等.Cr系丙烷脱氢催化剂研究进展[J].化工进展,2010,29(1):51-57. [17] 吴同旭,杨玉旺,蔡奇,等.CrOx/Al2O3丙烷脱氢催化剂性能研究[J].天然气化工:C1化学与化工,2016,41(3):16-20. [18] Kumar M S,Hammer N,Rønning M,et al.The nature of active chromium species in Cr-catalysts for dehydrogenation of propane:New insights by a comprehensive spectroscopic study[J].Journal of Catalysis,2009,261(1):116-128. [19] Wȩgrzyniak A,Jarczewski S,Wach A,et al.Catalytic behaviour of chromium oxide supported on CMK-3 carbon replica in the dehydrogenation propane to propene[J].Applied Catalysis A:General,2015,508:1-9. [20] 蔡奇,杨玉旺,吴同旭,等.Mg对Cr2O3/Al2O3催化剂及其丙烷脱氢性能的影响[J].石油炼制与化工,2016,47(3):72-76. [21] Li P P,Lang W Z,Xia K,et al.The promotion effects of Ni on the properties of Cr/Al catalysts for propane dehydrogenation reaction[J].Applied Catalysis A:General,2016,522:172-179. [22] Cabrera F,Ardissone D,Gorriz O F.Dehydrogenation of propane onchromia/alumina catalysts promoted by tin[J].Catalysis Today,2008,133:800-804. [23] Chen M,Xu J,Yong C,et al.Dehydrogenation of propane over In2O3-Al2O3 mixed oxide in the presence of carbon dioxide[J].Journal of Catalysis,2010,272(1):101-108. [24] Otroshchenko T,Kondratenko V A,Rodemerck U,et al.ZrO2-based unconventional catalysts for non-oxidative propane dehydrogenation:Factors determining catalytic activity[J].Journal of Catalysis,2017,348:282-290. [25] Wang G W,Zhang H L,Wang H R,et al.The role of metallic Sn species in catalytic dehydrogenation of propane:Active component rather than only promoter[J].Journal of Catalysis,2016,344:606-608. [26] Vu B K,Song M B,Ahn I Y,et al.Location and structure of coke generated over Pt-Sn/Al2O3 in propane dehydrogenation[J].Journal of Industrial and Engineering Chemstry,2011,17(1):71-76. [27] Li Q,Sui Z J,Zhou X G,et al.Coke formation on Pt-Sn/Al2O3 catalyst in propane dehydrogenation:Coke characterization and kinetic study[J].Topics in Catalysis,2011,54:888-896. [28] Gascón J,Téllez C,Herguido J,et al.Propane dehydrogenation over a Cr2O3/Al2O3,catalyst:Transient kinetic modeling of propene and coke formation[J].Applied Catalysis A:General,2003,248:105-116. [29] Nijhuis T A,Tinnemans S J,Visser T,et al.Towards real-time spectroscopic process control for the dehydrogenation of propane over supported chromium oxide catalysts[J].Chemical Engineering Science,2004,59:5487-5492.